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학술지 Rapid and Ecofriendly Esterification of Alcohols with 2-Acylpyridazinones
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저자
김보람, 성기현, 류기은, 김점종, 윤용진
발행일
201311
출처
Bulletin of the Korean Chemical Society, v.34 no.11, pp.3410-3414
ISSN
0253-2964
출판사
대한화학회 (KCS)
DOI
https://dx.doi.org/10.5012/bkcs.2013.34.11.3410
협약과제
13ZC1200, 그린IT 융.복합 기술개발, 이수인
초록
Atom-economical esterification is of great importance in green chemistry. In this work, we demonstrated the catalyst and additive free esterification of alcohols by their reaction with 2-acyl-4,5-dichloropyridazin-3(2H)- ones without solvent at 100 oC. Aliphatic and aromatic alcohols were converted into the corresponding esters in good to excellent yields. It is noteworthy that the reaction is solvent-free, atom-economic, easy-workup, and rapid and that the process is inexpensive.
키워드
2-Acylpyridazin-3(2H)-one, Atom-economical reaction, Esterification, Green chemistry, Heterocycles
KSP 제안 키워드
Aromatic alcohols, Green chemistry, additive free, solvent-free