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학술지 Tert-Butoxide-Assisted Amidation of Esters under Green Conditions
Cited 67 time in scopus Download 1 time Share share facebook twitter linkedin kakaostory
저자
김보람, 이형근, 강성범, 성기현, 김점종, 박종근, 이상경, 윤용진
발행일
201201
출처
Synthesis, v.44 no.1, pp.42-50
ISSN
0039-7881
출판사
Synthesis
DOI
https://dx.doi.org/10.1055/s-0031-1289622
협약과제
12ZK1100, 그린IT 융.복합 기술개발, 이수인
초록
Efficient and green amidation reactions are of great importance. In this work, we demonstrate the tert-butoxide-assisted amidation of esters with amines under ambient conditions. Aliphatic and/or aromatic esters were converted into the corresponding amides under mild conditions in good to excellent yields. It is noteworthy that the reaction is highly efficient, rapid, versatile, green and economical, and will find great practical application in organic synthesis, biochemistry, and industrial chemistry. © Georg Thieme Verlag Stuttgart. New York.
키워드
amidation, amides, esters, potassium tert -butoxide, radicals
KSP 제안 키워드
Aromatic esters, Industrial chemistry, ambient conditions, highly efficient, mild conditions, organic synthesis, potassium tert -butoxide, practical application, tert-butoxide(Niobium penta)