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Journal Article In Situ-Grown Hexagonal Silicon Nanocrystals in Silicon Carbide-Based Films
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Authors
Tae-Youb Kim, Chul Huh, Nae-Man Park, Cheol-Jong Choi, Maki Suemitsu
Issue Date
2012-12
Citation
Nanoscale Research Letters, v.7, pp.1-5
ISSN
1931-7573
Publisher
Springer
Language
English
Type
Journal Article
DOI
https://dx.doi.org/10.1186/1556-276X-7-634
Abstract
Silicon nanocrystals (Si-NCs) were grown in situ in carbide-based film using a plasmaenhanced chemical vapor deposition method. High-resolution transmission electron microscopy indicates that these nanocrystallites were embedded in an amorphous silicon carbide-based matrix. Electron diffraction pattern analyses revealed that the crystallites have a hexagonal-wurtzite silicon phase structure. The peak position of the photoluminescence can be controlled within a wavelength of 500 to 650 nm by adjusting the flow rate of the silane gas. We suggest that this phenomenon is attributed to the quantum confinement effect of hexagonal Si-NCs in silicon carbide-based film with a change in the sizes and emission states of the NCs. © 2012 Kim et al.
KSP Keywords
Amorphous silicon carbide, Chemical vapor deposition method, Electron diffraction pattern, Electron microscopy(SEM), Flow rate, Peak position, Phase Structure, Quantum confinement effect, Silicon nanocrystals(Si NCs), Transmission Electron Microscopy(TEM), high-resolution transmission electron microscopy(HRTEM)
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