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학술지 Stimuli-Responsive Magneto-/Electro-Chromatic Color-Tunable Hydrophobic Surface Modified Fe3O4@SiO2 Core-Shell Nanoparticles for Reflective Display Approaches
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저자
이서주*, 김주연*, 전상훈, 김수정, 김덕기, 류호준
발행일
201701
출처
RSC Advances, v.7 no.12, pp.6988-6993
ISSN
2046-2069
출판사
Royal Society of Chemistry (RSC)
DOI
https://dx.doi.org/10.1039/c6ra27540k
협약과제
14PB6200, 풀컬러 색변환 전자스킨을 위한 콜로이드 광결정 필름 소재 개발, 류호준
초록
In order to provide stimuli-responsive properties under magnetic- and electric-forces enabling reflective color-changes in a liquid medium, the surface of silica coated-iron oxide core-shell nanoparticles (Fe3O4@SiO2) is successfully modified with two-different types of silane coupling agents to improve the dispersion stability as well as the color change strength as a result of the effectively increased repulsion. A stimuli-responsive magneto- and electro-chromatic ink is prepared by mixing hydrophobic surface modified Fe3O4@SiO2-Fx (x = 0 and 13) core-shell nanoparticles and a dispersing agent in a low dielectric medium (LDM). The magneto-chromatic and electro-chromatic stimuli-responsive properties are visually confirmed. Moreover, the optical reflective color spectra and color gamut calculated from the CIE chromaticity coordinates of the hydrophobic surface modified Fe3O4@SiO2-F13 core-shell nanoparticles (with "F moiety" in the molecular structure) under an applied voltage range of 0 V to 10 V show that the hydrophobic surface modified magnetite nanoparticles are promising candidates for reflective display applications.
KSP 제안 키워드
CIE chromaticity coordinates, Color changes, Color tunable, Dielectric medium, Dispersing agent, Display applications, Hydrophobic surface, Liquid medium, Low dielectric, Magneto-chromatic, Modified magnetite nanoparticles