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Journal Article Rapid and Ecofriendly Esterification of Alcohols with 2-Acylpyridazinones
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Authors
Bo Ram Kim, Gi Hyeon Sung, Ki Eun Ryu, Jeum-Jong Kim, Yong-Jin Yoon
Issue Date
2013-11
Citation
Bulletin of the Korean Chemical Society, v.34, no.11, pp.3410-3414
ISSN
0253-2964
Publisher
대한화학회 (KCS)
Language
English
Type
Journal Article
DOI
https://dx.doi.org/10.5012/bkcs.2013.34.11.3410
Abstract
Atom-economical esterification is of great importance in green chemistry. In this work, we demonstrated the catalyst and additive free esterification of alcohols by their reaction with 2-acyl-4,5-dichloropyridazin-3(2H)- ones without solvent at 100 oC. Aliphatic and aromatic alcohols were converted into the corresponding esters in good to excellent yields. It is noteworthy that the reaction is solvent-free, atom-economic, easy-workup, and rapid and that the process is inexpensive.
KSP Keywords
Aromatic alcohols, additive free, green chemistry, solvent-free