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Journal Article
Construction and Characterization of Novel Molecular Architectures Through Coordination-Driven Self-Assembly: Rhomboid and Overlapped Double Rhomboid
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- Authors
- Jeum-Jong Kim, Ock Keum Kwak, Jong Keun Park, Kil Sik Min, Yong-Jin Yoon
- Issue Date
- 2014-08
- Citation
- Journal of Inclusion Phenomena and Macrocyclic Chemistry, v.79, no.3-4, pp.495-502
- ISSN
- 1388-3127
- Language
- English
- Type
- Journal Article
- Project Code
- 13ZC1200, Green IT convergence Technologies Development, Lee Soo In
- Abstract
- The potentially tridentate ligands 4-(6-(pyridin-4-yl)pyridin-2-yl)pyridine (4) and 3-(6-(pyridin-3-yl)-pyridin-2-yl)pyridine (5) have been prepared and characterized. From the self-assembly of 4 or 5 and 2,9-bis[trans-Pt(PEt 3)2(NO3)]phenanthrene (6), two supramolecular platinum-based macrocycles with rhomboid (7) and overlapped double rhomboid (8) structures have been constructed. Compounds 7 and 8 are formed in different shapes due to the different nitrogen positions (meta and para) of the ligands 4 and 5, respectively. Both supramolecules are characterized by multinuclear NMR and electrospray ionization mass spectroscopies. © 2013 Springer Science+Business Media Dordrecht.