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Journal Article Fast Diffusion Supercapacitors Via an Ultra-High Pore Volume of Crumpled 3D Structure Reduced Graphene Oxide Activation
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Authors
Keunsik Lee, Doyoung Kim, Yeoheung Yoon, Junghee Yang, Ho-Gyeong Yun, In-Kyu You, Hyoyoung Lee
Issue Date
2015-07
Citation
RSC Advances, v.5, no.75, pp.60914-60919
ISSN
2046-2069
Publisher
Royal Society of Chemistry (RSC)
Language
English
Type
Journal Article
DOI
https://dx.doi.org/10.1039/c5ra10246d
Abstract
In order to obtain a high performance supercapacitor, there are several factors that must be achieved including a high specific surface area (SSA), high electrical conductivity, and a high diffusion rate of the electrolyte due to an appropriate pore volume. Herein, we report a high performance supercapacitor using activated non-stacked reduced graphene oxide (a-NSrGO) that has a high SSA (up to 999.75 m2 g-1) with intrinsic high graphene conductivity (1202 S m-1) and fast diffusion of the electrolyte. Due to a high total pore volume (5.03 cm3 g-1) and a wide pore size distribution from macro- to micropores (main pore width: 0.61 - 0.71 nm) in the a-NSrGO sheets, the as-prepared a-NSrGO electrode shows high specific capacitance (105.26 F g-1) and a short relaxation time (??0 = 1.5 s) in a propylene carbonate (PC)-based organic electrolyte. A maximum energy density of 91.13 W h kg-1 and a power density of 66 684.73 W kg-1 were estimated in a fully packaged coin cell. The high performance of the a-NSrGO supercapacitors is attributed to their specific appearance and enlarged pore distribution with high SSA.
KSP Keywords
3D structure, Diffusion rate, Electrical conductivity(EC), Fast diffusion, Graphene oxide(GOS), High Specific Capacitance, High electrical conductivity, High specific surface area, High-performance supercapacitors, Pore Size Distribution, Pore distribution