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학술지 Two-Step Selenization of Cu-In-Ga Precursors for CIGS Thin-Film Solar Cells by Using a Se Cracker
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저자
이호섭, 박래만, 이규석, 김제하, 장호정
발행일
201205
출처
Journal of the Korean Physical Society, v.60 no.10, pp.1753-1756
ISSN
0374-4884
출판사
한국물리학회
DOI
https://dx.doi.org/10.3938/jkps.60.1753
협약과제
11MB3100, 반응성 스퍼터링을 이용한 CIGS 초박막 고효율 태양전지 기술 개발, 김제하
초록
Cu(In 1-xGa x)Se 2 (CIGS) thin-film solar cells have been fabricated using the CIGS compound prepared with a two-step selenization process at 400 °C followed by successive thermal annealing at 550 °C. The compositions of the Cu-In-Ga precursors were controlled by changing the thickness ratio of the Cu-In and the Cu-Ga films. After the selenization, the thickness of the CIGS film was approximately three times that of the precursor layer. X-ray diffraction peaks showed that the CIGS had the chalcopyrite structure with a preferential orientation in the (112) direction. The composition analysis using X-ray fluorescence revealed that the Cu/[III] and the Ga/[III] ratios of CIGS changed in ranges of 0.66 ~ 0.80 and 0.11 ~ 0.20, respectively, with variations in the precursor thickness. We obtained a power conversion efficiency of 3.91% from the fabricated CIGS solar cell. © 2012 The Korean Physical Society.
KSP 제안 키워드
CIGS film, CIGS solar cell, Chalcopyrite structure, Conversion efficiency(C.E.), Diffraction peaks, Precursor layer, Preferential orientation, Selenization process, Thermal annealing, Thickness ratio, Thin film solar cells