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Journal Article Tert-Butoxide-Assisted Amidation of Esters under Green Conditions
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Authors
Bo Ram Kim, Hyung-Geun Lee, Seung-Beom Kanga, Gi Hyeon Sung, Jeum-Jong Kim, Jong Keun Park, Sang-Gyeong Lee, Yong-Jin Yoon
Issue Date
2012-01
Citation
Synthesis, v.44, no.1, pp.42-50
ISSN
0039-7881
Publisher
Synthesis
Language
English
Type
Journal Article
DOI
https://dx.doi.org/10.1055/s-0031-1289622
Project Code
12ZK1100, Green IT convergence Technologies Development, Lee Soo In
Abstract
Efficient and green amidation reactions are of great importance. In this work, we demonstrate the tert-butoxide-assisted amidation of esters with amines under ambient conditions. Aliphatic and/or aromatic esters were converted into the corresponding amides under mild conditions in good to excellent yields. It is noteworthy that the reaction is highly efficient, rapid, versatile, green and economical, and will find great practical application in organic synthesis, biochemistry, and industrial chemistry. © Georg Thieme Verlag Stuttgart. New York.
KSP Keywords
Aromatic esters, Industrial chemistry, ambient conditions, highly efficient, mild conditions, organic synthesis, practical application, tert-butoxide(Niobium penta)