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학술대회 Characterization of Nafion Solid Polymer Elecrolyte for an Electrochemical Sensor using Scnanning Probe Microscopy and Electrochemical Impedance Spectroscopy
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저자
박종혁, 문승언, 김은경, 이홍열, 박강호
발행일
200610
출처
IEEE Sensors 2006, pp.1261-1264
DOI
https://dx.doi.org/10.1109/ICSENS.2007.355853
협약과제
06MB3100, 유비쿼터스 단말용 부품 모듈, 김종대
초록
Solid polymeric electrolyte Nafion film was studied using electrical and microscopic method based on scanning probe microscope (SPM) and electrochemical impedance spectroscopy (EIS). This thin film upon proper treatment was found to have ionic conductivity comparable to liquid electrolyte. Hence, to integrate an electrical device into a smaller sized platform, for example, electrochemical sensor or fuel cell, this material can be a best choice due to lower processing temperature, easy handling and less weight compared with other solid oxide electrolytes. Since it was based on the polymer constituent, however, the stability and lifetime during operation should be improved to outdo other competitors. Aiming at this goal, we have tried the electrical and structural characterization of Nafion film under hydration. Our SPM tool could easily reveal the significant change down to a nanometer scale of the structure and electrical property of Nafion film along the subsequent process and give the basic understanding of the effect on the performance and the long-term stability of the device. © 2006 IEEE.
KSP 제안 키워드
Electrical devices, Impedance spectroscopy(IS), Liquid electrolyte, Long-Term Stability, Nafion film, Nanometer-scale, Probe microscopy, Processing temperature, Scanning probe microscope(SPM), Solid oxide electrolytes, Solid polymeric electrolyte