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학술지 The Characterization of Nanocrystalline Dye-Sensitized Solar Cells with Flexible Metal Substrates by Electrochemical Impedance Spectroscopy
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저자
전용석, 강만구
발행일
200701
출처
Journal of the Electrochemical Society, v.154 no.1, pp.B68-B71
ISSN
0013-4651
출판사
Electrochemical Society (ECS)
DOI
https://dx.doi.org/10.1149/1.2374943
협약과제
06MB3100, 유비쿼터스 단말용 부품 모듈, 김종대
초록
Metal substrates are excellent alternatives to conducting plastic substrates in flexible solar cells because of the possible sintering process at high temperature. However, the investigation of cells with flexible metal substrates has only recently started with titanium, tungsten, and stainless steel. It was found that they formed semiconductor oxides after the sintering process. In this paper, we probed the properties of dye sensitized solar cells with the metal substrates prepared in three different ways-a bare metal sheet, indium tin oxide (ITO) sputter coating on a bare metal sheet, and ITO sputter coating after the addition of a SiOx layer on the metal sheet. The best cell efficiency was obtained from the cell with bare Ti because it formed a TiO2 layer which was identical to the main working electrode. When an ITO layer was added, fill factors (FFs) increased for W and SUS 304 and FF decreased for Ti; the addition of a SiOx layer led to a short circuit current increase and FF decrease. Electrochemical impedance spectroscopy was taken and analyzed to characterize the resistance element in each circuit, and the corresponding effects were discussed. A new impedance element resulting from the SiOx insulating layer was classified from electrochemical impedance spectroscopic data. © 2006 The Electrochemical Society.
KSP 제안 키워드
Bare Metal, Cell Efficiency, Dye-sensitized solar cells(DSCs), Electrochemical impedance spectroscopic, High Temperature, Impedance spectroscopy(IS), Metal sheet, Plastic substrate, Semiconductor oxides, Short-Circuit Current, Sintering process