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Journal Article Microscopic Behavior of Sb in Chalcogenide Materials for Crystallization Process
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Authors
Ho Jun Ryu, Yong Goo Yoo, Mun Cheol Paek, Kwang Yong Kang
Issue Date
2007-03
Citation
Materials Science and Engineering A, v.449-451, pp.573-577
ISSN
0921-5093
Publisher
Elsevier
Language
English
Type
Journal Article
DOI
https://dx.doi.org/10.1016/j.msea.2006.02.421
Abstract
The microscopic behavior of the chalcogenides materials alloys has been investigated for the understanding of the crystallization process. To analyze the crystallization-amorphization temperature by endo-exothermic process differential scanning calorimetry is carried out. Knowing the crystallization activation energy, we have performed in situ transmission electron microscopy with heating-rate change. With increasing temperature, as-deposited amorphous films transform to the crystalline phase, and Sb depletion takes place near 573 K. For the calculation of activation energy, the measured data obtained from heating-rate changes is plotted according to the Kissinger equation. The crystallization activation energy of the chalcogenide material is 2.03 짹 0.2 eV. © 2006 Elsevier B.V. All rights reserved.
KSP Keywords
Amorphous films, As-deposited, Chalcogenide material, Crystallization activation energy, Differential scanning calorimetry(photo-DSC), Exothermic process, Increasing temperature, Kissinger equation, Microscopic behavior, Scanning calorimetry(DSC), Transmission Electron Microscopy(TEM)