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학술지 Microscopic Behavior of Sb in Chalcogenide Materials for Crystallization Process
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저자
류호준, 유용구, 백문철, 강광용
발행일
200703
출처
Materials Science and Engineering A, v.449-451, pp.573-577
ISSN
0921-5093
출판사
Elsevier
DOI
https://dx.doi.org/10.1016/j.msea.2006.02.421
협약과제
06MB3500, 유비쿼터스용 CMOS 기반 MEMS 복합센서기술개발, 최창억
초록
The microscopic behavior of the chalcogenides materials alloys has been investigated for the understanding of the crystallization process. To analyze the crystallization-amorphization temperature by endo-exothermic process differential scanning calorimetry is carried out. Knowing the crystallization activation energy, we have performed in situ transmission electron microscopy with heating-rate change. With increasing temperature, as-deposited amorphous films transform to the crystalline phase, and Sb depletion takes place near 573 K. For the calculation of activation energy, the measured data obtained from heating-rate changes is plotted according to the Kissinger equation. The crystallization activation energy of the chalcogenide material is 2.03 짹 0.2 eV. © 2006 Elsevier B.V. All rights reserved.
KSP 제안 키워드
Amorphous films, As-deposited, Chalcogenide material, Crystallization activation energy, Differential scanning calorimetry(photo-DSC), Exothermic process, Increasing temperature, Kissinger equation, Microscopic behavior, Scanning calorimetry(DSC), Transmission Electron Microscopy(TEM)