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Journal Article Kinetics of Chemical Changes in Phenol Formaldehyde Based Polymeric Films Etched in N2 O and O2 Inductively Coupled Plasmas: A Comparative Study
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Authors
Kwang Ho Kwon, Nam Ki Min, Seung Youl Kang, Kyu Ha Baek, Kyung Soo Suh, Dmitriy Alexandrovich Shutov
Issue Date
2009-09
Citation
Japanese Journal of Applied Physics, v.48 no.8, pp.1-4
ISSN
0021-4922
Publisher
Japan Society of Applied Physics (JSAP), Institute of Physics (IOP)
Language
English
Type
Journal Article
DOI
https://dx.doi.org/10.1143/JJAP.48.08HA02
Project Code
08IB3500, 인쇄 소재의 TFT 특성 연구, Baek Kyu-Ha
Abstract
This paper reports on investigation of surface chemistry and etch rates of phenol formaldehyde based polymer after N2O and O2 radio frequency (RF) inductively coupled plasma processing depend on exposure time. By using X-ray photoelectron spectroscopy, it was shown that oxygen and nitrogen oxide plasma expositions both lead to similar changes in the chemical composition of polymer. The nitrogen oxide plasma does not lead to any significant increase of concentration of nitrogen-containing groups on the polymer. It was confirmed that the mechanism of photoresist destruction in the N2O discharge was generally identical to that in the O2 plasma. Furthermore, the surface interactions with the polymer of nitrogen-containing active species could be neglected. © 2009 The Japan Society of Applied Physics.
KSP Keywords
Applied physics, Chemical changes, Etch rates, Exposure time, Inductively-coupled plasma(ICP), Nitrogen oxide, Nitrogen-containing, O and O, Polymeric films, Surface chemistry, X-ray Photoelectron Spectroscopy