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학술지 Organic Vapor-Jet-based Route for Solvent-Free Additive Formation of Oxide Semiconductors
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저자
최정민, 김성연, 권혁윤, 김민철, 문한을, 박종혁, 유승협
발행일
201704
출처
Organic Electronics, v.43, pp.235-239
ISSN
1566-1199
출판사
Elsevier
DOI
https://dx.doi.org/10.1016/j.orgel.2017.01.033
협약과제
16PB1400, 대면적 그래핀 기판을 이용한 저비용, 고품위의 III-V 나노와이어 발광소자 개발, 박종혁
초록
We demonstrate a novel solution-free technique which can be used to print metal oxide patterns without masks by adopting an organic vapor jet printing (VJP) method. To avoid the high deposition temperatures required for metal oxide vaporization, metal-organic compounds are first jet-printed as metal-oxide precursors and converted into metal oxides by a photo-conversion process. As an example, we show that indium oxides can easily be prepared from jet-printed films of indium acetylacetonate upon photo-conversion; the effectiveness of which is supported by X-ray photoelectron spectroscopy (XPS) showing a reduction of the carbon portion associated with the alkyl chains of the precursors. A carrier mobility of 4.5혻cm2/V쨌s and an on/off ratio of 105 are demonstrated in the oxide thin-film transistors based on indium oxides prepared by the proposed method, illustrating the potential usefulness of this process in electronic device fabrication.
KSP 제안 키워드
Carrier mobility, High deposition, Metal-oxide(MOX), Organic vapor jet printing, Oxide patterns, Oxide precursors, Oxide semiconductor, Photo-conversion, Thin-Film Transistor(TFT), X-ray photoelectron spectroscopy (xps), alkyl chains