A new structure of stretchable and transparent metal-grid electrodes is described, where a liquid metal alloy, eutectic gallium-indium (EGaIn) is employed as a stretchable conducting material. By a 'roll-painting and lift-off' technique based on photolithography, stretchable EGaIn-grids with the linewidth of 20 μm and the line pitch of 400-1000 μm are produced, providing the transmittance of 75%-88% with the sheet resistance less than 2.3 廓 square. Powered by the freely deformable nature of the liquid phase conductor, the EGaIn-grid provides stable conductivity under highly stretched condition up to 40%, as well as high reliability against cyclic deformation. By combining the EGaIn-grid with a homogeneous and transparent poly(3,4-thylenedioxythiophene):poly(styrensulfonate) (PEDOT:PSS) layer in a hybrid manner, we can construct highly stretchable and uniformly conducting transparent electrodes. The hybrid PEDOT:PSS/EGaIn-grid electrodes can be utilized as electrodes for a stretchable inorganic electroluminescence device with a ZnS phosphor-elastomer composite as the emission layer, which maintains uniform and stable emission under highly and repeatedly stretched conditions.
KSP Keywords
Conducting materials, Elastomer composite, High Reliability, Line pitch, Liquid metal alloy, Metal grids, ZnS phosphor, cyclic deformation, eutectic gallium-indium, highly stretchable, lift-off
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