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Journal Article Highly Efficient Ag-alloyed Cu(In,Ga)Se2 Solar Cells with Wide Bandgaps and Their Application to Chalcopyrite-based Tandem Solar Cells
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Authors
Kihwan Kim, Seung Kyu Ahn, Jang Hoon Choi, Jinsoo Yoo, Young-Joo Eo, Jun-Sik Cho, Ara Cho, Jihye Gwak, Soomin Song, Dae-Hyung Cho, Yong-Duck Chung, Jae Ho Yun
Issue Date
2018-06
Citation
Nano Energy, v.48, pp.345-352
ISSN
2211-2855
Publisher
Elsevier
Language
English
Type
Journal Article
DOI
https://dx.doi.org/10.1016/j.nanoen.2018.03.052
Project Code
17JB1600, Development of colorful flexible thin film solar cells with nontoxic buffer layer, Chung Yong-Duck
Abstract
In this work, Ag alloying effects in wide-bandgap Cu(In,Ga)Se2 (CIGS) solar cells are investigated, and their application in tandem solar cells is attempted. With a three-stage process, highly efficient Ag-alloyed CIGS (ACIGS) solar cells with Eg ?돟 1.4 eV are fabricated; the benefits of Ag alloying are discussed with a focus on the control of structural/electronic disorders. The ACIGS solar cells are found to exhibit particularly improved device performance in specific compositions; in general, Ag alloying helps to enhance VOC in wide-bandgap CIGS solar cells. With wide-bandgap ACIGS cells as a top subcell, various kinds of chalcopyrite-based tandem (two-junction and two-terminal) cells are demonstrated. Prospects and limitations of chalcopyrite-based tandem cells are investigated by examining beam-splitting tandem, mechanically stacked tandem, and monolithic tandem cells.
KSP Keywords
Alloying effects, Beam splitting, CIGS solar cell, Wide Band Gap, device performance, highly efficient, monolithic tandem, tandem cell, tandem solar cell, three-stage process, two-terminal