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학술지 Fabrication of Highly Transparent Electrochromic Mirror Device with Nanoporous Counter Electrode
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아칠성, 송주희, 조성목, 김태엽, 류호준, 전상훈, 김수정, 김주연, 김용해, 황치선
Bulletin of the Korean Chemical Society, v.39 no.10, pp.1186-1192
대한화학회 (KCS), Wiley
18HB1600, 고해상도 광대역 실감 입체 영상용 소재 및 소자 기술, 김태엽
A new inorganic?뱋rganic hybrid electrochromic mirror device was fabricated, which is very transparent; its transparency and optical and electrical properties are highly influenced by the structure of the counter electrode (CE). The working electrode (WE) was fabricated via vacuum deposition of Ag, ITO, and WO3 films on glass, in sequence. Ag, ITO, and WO3 served as mirror and low resistance electrode, Ag protective layer, and inorganic reduction electrochromic layer, respectively. This study used a flat CE and nanoporous structured CE that had greatly increased surface to volume ratio. Flat CE did not reduce portion of oxidized phenothiazine (PH). In decoloration state, mirror device still had reddish color; this was a factor that decreased the decoloration reflectance. On the other hand, the use of nanoporous structured CE reduced the entire amount of oxidized PH, completely eliminated the reddish color, and enabled the fabrication of highly reflective mirror devices. Moreover, the use of nanoporous structured CE improved the electrochromic optical and electrical properties, leading to high reflectance variation, low consumed charge, low coloration static current, and fast response time compared to those characteristics of flat CE.
KSP 제안 키워드
Low resistance electrode, Optical and electrical properties, Protective layer, Volume ratio, Working electrode, counter electrode, electrical properties(I-V curve), fast response time, high reflectance, highly transparent, static current