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학술지 ZnO-CuO Core-Hollow Cube Nanostructures for Highly Sensitive Acetone Gas Sensors at the ppb Level
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저자
이재은, 임찬규, 박형주, 송현준, 최성율, 이대식
발행일
202008
출처
ACS Applied Materials & Interfaces, v.12 no.31, pp.35688-35697
ISSN
1944-8244
출판사
American Chemical Society (ACS)
DOI
https://dx.doi.org/10.1021/acsami.0c08593
협약과제
20JR1100, 다중 바이오마커 기반 모바일 다이어트 모니터링 기술 개발, 이대식
초록
This paper presents a ZnO-CuO p-n heterojunction chemiresistive sensor that comprises CuO hollow nanocubes attached to ZnO spherical cores as active materials. These ZnO-CuO core-hollow cube nanostructures exhibit a remarkable response of 11.14 at 1 ppm acetone and 200 °C, which is a superior result to those reported by other metal-oxide-based sensors. The response can be measured up to 40 ppb, and the limit of detection is estimated as 9 ppb. ZnO-CuO core-hollow cube nanostructures also present high selectivity toward acetone against other volatile organic compounds and demonstrate excellent stability for up to 40 days. The outstanding gas-sensing performance of the developed nanocubes is attributed to their uniform and unique morphology. Their core-shell-like structures allow the main charge transfer pathways to pass the interparticle p-p junctions, and the p-n junctions in each particle increase the sensitivity of the reactions to gas molecules. The small grain size and high surface area of each domain also enhance the surface gas adsorption.
키워드
acetone detection, hybrid nanostructure, metal oxide semiconductor, p-n junction, ultrasensitive gas sensor
KSP 제안 키워드
Active materials, Charge transfer, Chemiresistive sensor, Gas adsorption, Gas molecules, Highly sensitive, Limit of detection, Metal-oxide(MOX), P-N junction, Petri net(PN), Small grain size