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Journal Article Identification of a Multi-stack Structure of Graphene Electrodes Doped Layer-by-layer with Benzimidazole and Its Implication for the Design of Optoelectronic Devices
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Authors
Hyunsu Cho, Jinouk Song, Jin-Wook Shin, Jaehyun Moon, Byoung-Hwa Kwon, Jeong-Ik Lee, Seunghyup Yoo, Nam Sung Cho
Issue Date
2021-07
Citation
Optics Express, v.29, no.15, pp.23131-23141
ISSN
1094-4087
Publisher
Optical Society of America (OSA)
Language
English
Type
Journal Article
DOI
https://dx.doi.org/10.1364/OE.430149
Abstract
Optical properties of benzimidazole (BI)-doped layer-by-layer graphene differ significantly from those of intrinsic graphene. Our study based on transmission electron microscopy and X-ray photoelectron spectroscopy depth profiling reveals that such a difference stems from its peculiar stratified geometry formed in situ during the doping process. This work presents an effective thickness and optical constants that can treat these multi-stacked BI-doped graphene electrodes as a single equivalent medium. For verification, the efficiency and angular emission spectra of organic light-emitting diodes with the BI-doped graphene electrode are modeled with the proposed method, and we demonstrate that the calculation matches experimental results in a much narrower margin than that based on the optical properties of undoped graphene.
KSP Keywords
Bi-doped, Depth profiling(DP), Doping process, Effective thickness, Electron Microscopy(TEM and SEM), Equivalent medium, Light-emitting diodes(LED5), Multi-stack, Optical constants, Organic light-emitting diodes(OLED), Stack structure
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