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Journal Article Extremely Stable Ag‐Based Photonics, Plasmonic, Optical, and Electronic Materials and Devices Designed with Surface Chemistry Engineering for Anti‐Tarnish
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Authors
Junhyuk Ahn, Doa Kim, Junhyeok Park, Yoonji Yang, Mi-Hyun Kim, Hyung Jin Choi, Wooseok Jeong, Woo Seok Lee, Dae Yang Oh, Don-Hyung Ha, Sung-Hoon Hong, Soong Ju Oh
Issue Date
2024-08
Citation
Small, v.20, no.31, pp.1-10
ISSN
1613-6810
Publisher
Wiley - V C H Verlag GmbbH & Co.
Language
English
Type
Journal Article
DOI
https://dx.doi.org/10.1002/smll.202308968
Abstract
Silver (Ag) metal‐based structures are promising building blocks for next‐generation photonics and electronics owing to their unique characteristics, such as high reflectivity, surface plasmonic resonance effects, high electrical conductivity, and tunable electron transport mechanisms. However, Ag structures exhibit poor sustainability in terms of device performance because harsh chemicals, particularly S2− ions present in the air, can damage their structures, lowering their optical and electrical properties. Here, the surface chemistry of Ag structures with (3‐mercaptopropyl)trimethoxysilane (MPTS) ligands at room temperature and under ambient conditions is engineered to prevent deterioration of their optical and electrical properties owing to S2− exposure. Regardless of the dimensions of the Ag structures, the MPTS ligands can be applied to each dimension (0D, 1D, and 3D). Consequently, highly sustainable plasmonic effects (Δλ < 2 nm), Fabry–Perot cavity resonance structures (Δλ < 2 nm), reflectors (ΔRReflectance < 0.5%), flexible electrodes (ΔRelectrical < 0.1 Ω), and strain gauge sensors (ΔGF < 1), even in S2− exposing conditions is achieved. This strategy is believed to significantly contribute to environmental pollution reduction by decreasing the volume of electronic waste.
KSP Keywords
Building block, Cavity resonance, Electrical conductivity(EC), Electron Transport, Electronic materials and devices, Electronic waste, Environmental pollution, High electrical conductivity, High reflectivity, Optical and electrical properties, Plasmonic effect