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Journal Article
Reliable and Reusable All‐Solid‐State Contact‐Type Pre‐Lithiation Platform for High‐Performance All‐Solid‐State Batteries
- Authors
- Yunho Lee, Yongjun Kwon, Juhyeong Noh, Seok Hun Kang, Kyubeen Kang, Junhyeok Choi, Young-Gi Lee, Jaecheol Choi, Hyeong Min Jin, Yong Min Lee, Ju Young Kim
- Citation
- Advanced Materials, Early Access
- ISSN
- 0935-9648
- Publisher
- John Wiley & Sons
- Language
- English
- Type
- Journal Article
- Abstract
- All‐solid‐state batteries represent a promising approach for achieving high energy density and enhanced safety by utilizing bipolar cell architectures and nonflammable solid electrolytes. However, lithium loss during initial cycling occurs primarily due to the limited electrochemical stability of solid electrolytes and the irreversibility of anode materials with high theoretical capacities, resulting in a lower achievable energy density than theoretically expected. Additionally, all‐solid‐state batteries are highly sensitive to interfacial phenomena, which makes addressing these challenges crucial for maximizing their electrochemical performance. In this study, we introduce a reliable and reusable contact‐type pre‐lithiation platform specifically designed for all‐solid‐state systems. This platform, consisting of solid electrolytes and electron‐conductive agents, exhibits balanced ionic and electronic transport characteristics, enabling uniform pre‐lithiation of all‐solid‐state electrodes through simple, reversible physical contact. Even under a low stack pressure of 8 MPa, pre‐lithiation can be effectively controlled by contact time and operating temperature, while the low stack pressure effectively suppresses the formation of highly resistive decomposition products at the interface. Consequently, the precisely pre‐lithiated anodes with optimized interfacial characteristics significantly enhance Coulombic efficiency during initial cycles and overall cycling performance, contributing to the realization of high‐performance all‐solid‐state batteries with genuinely high energy density.
- KSP Keywords
- Bipolar cell, Conductive agent, Contact time, Coulombic Efficiency, Electrochemical Stability, Electrochemical performance, Electronic Transport, High energy density, Interfacial characteristics, Interfacial phenomena, Lithium loss
This work is distributed under the term of Creative Commons License (CCL)
(CC BY)
(CC BY)
